Apr 152010
 

Cryst. Rev. (2010), 16(2), 133-144.    [ doi:10.1080/08893110903483238 ]

Recent developments in crystallographic error analysis are described. This report provides an introduction to more-formal work, originally published in Ref. (Haestier, J., J. Appl. Cryst. 2009, 42, 798). Prior to the main discussion, a brief overview of the normal distribution and error-propagation is … Read the rest

Apr 152010
 
BCA Spring Meeting 2010

Susan Huth presents Kirsten Christensen with the Durward Cruickshank Award

The final dinner of the British Crystallographic Association Spring Meeting in Warwick was interrupted, as always, with the prize winning awards. Amber Thompson was awarded the International Union of Crystallography Prize (a copy of International Tables) for her explanation of the advantages of choosing non-standard Read the rest

Dec 202009
 
Seizure: Crystallographic Art

Seizure

A dreary, grey, condemned, 1960s low-rise council flat is an unusual place to find one of the most beautiful pieces of crystallographic art in the UK.  “Seizure” was constructed by transforming the flat into a watertight tank, into which 70,000 litres of hot copper sulphate solution was poured.  After three weeks of patient … Read the rest

Nov 182009
 

Acta Cryst. (2009), C65, o635-o638.    [ doi:10.1107/S0108270109046952 ]

The unusual methylene aziridine 6-tert-butyl-3-oxa-2-thia-1-azabicyclo[5.1.0]oct-6-ene 2,2-dioxide, C9H15NO3S, was found to crystallize with two molecules in the asymmetric unit. The structure was solved in both the approximately orthogonal and the oblique settings of space group No. 14, viz. Read the rest

Oct 302009
 
Synthesis and Structural Studies of Gallium(III) and Indium(III) Complexes of 2-acetylpyridine Thiosemicarbazones (J. Chan, A. L. Thompson, M. W. Jones, J. M. Peach)

Inorg. Chim. Acta  (2010), 363(6), 1140-1149.    [ doi:10.1016/j.ica.2009.10.020 ]

Four 2-acetylpyridine 4N-alkyl thiosemicarbazones, and their Ga(III) and In(III) complexes have been prepared and characterised by fluorescence, UV–Vis, IR, 1H and 13C NMR spectroscopy, mass spectrometry and X-ray crystallographic analysis. Comparison of the crystal structures gave an insight into the nature of … Read the rest

Oct 222009
 

Acta Cryst. (2009), E65, o2904-o2905.    [ doi:10.1107/S1600536809043827 ]

X-ray crystallographic analysis of the title hydrobromide salt, C10H20N+Br-, of (1R,2S,3R,5R,8aR)-3-hydroxymethyl-5- methyloctahydroindolizine-1,2-diol defines the absolute and relative stereochemistry at the five chiral centres in steviamine, a new class of polyhydroxylated indolizidine alkaloid isolated from Stevia rebaudiana (Asteraceae) leaves.

Electronic reprint:

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Oct 072009
 
Nobel prize for Chemistry 2009 – The Structure of Ribosomes

The Nobel prize for chemistry has been jointly awarded to Venkatraman Ramakrishnan (MRC Cambridge), Thomas Steitz (Yale) and Ada Yonath (Weizmann Institute, Israel) for their work determining the structure of ribosomes.  The ribosome is an important component of cells that assembles proteins from amino acids.  It is often referred to as “the protein factory”.  This … Read the rest

Aug 212009
 

The 25th European Crystallographic Meeting was held in the Harbiye Museum and Cultural Centre in the beautiful city of Istanbul.  It was a very eventful week, and contributions to the conference made by Chem. Cryst. include:

N. David Brown, James Haestier, Mustapha Sadki, Amber L. Thompson & David J. Watkin
A Further Improved Structure Matching Read the rest

Aug 012009
 

J. Appl. Cryst. (2009), 42, 798-809.    [ doi:10.1107/S0021889809024376 ]

A new method is presented for handling errors on crystallographic data. In single-crystal diffraction experiments, two variance-covariance matrices are present, one for the cell parameters and the second for the refined parameters (atomic coordinates and anisotropic displacement parameters). These two matrices can be combined so … Read the rest